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Largest schools in Union County by level
- + Tennessee Virtual Academy Knoxville 路 Elementary 路 1,867 students
- + Maynardville Elementary Maynardville 路 Elementary 路 366 students
- + Luttrell Elementary Luttrell 路 Elementary 路 341 students
- + Paulette Elementary School Maynardville 路 Elementary 路 341 students
- + Tennessee Virtual Junior High School Knoxville 路 Middle 路 856 students
- + H Maynard Middle School Maynardville 路 Middle 路 604 students
- + Union County High School Maynardville 路 High 路 806 students
- + Union County Alternative Center Maynardville 路 High 路 30 students